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中国生物工程杂志

CHINA BIOTECHNOLOGY
中国生物工程杂志
中国生物工程杂志  2022, Vol. 42 Issue (11): 126-139    DOI: 10.13523/j.cb.2209044
生物质资源     
海蛎壳生物质资源再利用的研究进展*
张琪1,张益霞1,**(),薛彩丽1,张辉1,张云鹏1,杨大鹏2,**()
1 太原理工大学生物医学工程学院 太原 030024
2 泉州师范学院化工与材料学院 泉州 362000
Research Progress on Reuse of Biomass Resource of Oyster Shells
ZHANG Qi1,ZHANG Yi-xia1,**(),XUE Cai-li1,ZHANG Hui1,ZHANG Yun-peng1,YANG Da-peng2,**()
1 School of Biomedical Engineering, Taiyuan University Of Technology, Taiyuan 030024, China
2 School of Chemical Engineering and Materials, Quanzhou Normal University, Quanzhou 362000, China
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摘要：

海蛎是一种营养和医药价值较高的咸水双壳类动物,在世界各地被广泛养殖。海蛎壳副产品是一种天然生物质资源,由95%的碳酸钙和5%的有机基质组成。海蛎壳的多尺度、多层次“砖-泥”独特结构,使其具有良好的机械稳定性、生物相容性、可降解性和优异的吸附特性。首先,介绍了海蛎壳生物质的理化性质和天然独特微纳米结构,总结了海蛎壳在农业、工业、生物医药领域的研究现状,详细阐述了其在污水治理、土壤改良、天然抗菌剂(食品工业和生物医药)、骨组织工程、医药原料、生物填料、工业催化剂及分散载体、建筑工业填料、功能化涂料等领域的研究现状。其次,概述了利用生物转化技术将海蛎壳转化为生物能源、新型生物质材料等方面的研究进展。最后,展望了海蛎壳生物质资源及其衍生物未来在工业、农业、医药领域的潜在应用。
关键词： 海蛎壳生物资源;  水体修复;  土壤改良;  生物质抗菌;  工业生态原料    
Abstract:

Oysters are saltwater bivalves with high nutritional and medicinal value that are cultivated widely around the world. Oyster shell is a unique natural biomaterial composed of 95% calcium carbonate and 5% organic polymer material. Its unique multi-scale and multi-level “brick-mud”microstructure is similar to human hard tissues, which endows its good mechanical stability, biocompatibility, degradability, and excellent adsorption properties. Herein, this paper systematically introduces and discusses the physicochemical and highly ordered hierarchical natural unique calcium carbonate micro nano structure of oyster shell, followed by a summary of its applications in agriculture, industry and biology. Specially, we elaborate the applications of oyster shells in sewage processing, soil improvement, natural antibacterial agents (food industry and biomedicine), bone tissue engineering, medical uses, biological filling, catalysts and dispersive carriers in diesel industry, concrete fillers in construction industry, and functional coating additives,and introduce the advances in using the bioconversion technology to convert oyster shells into bioenergy, new biomass materials and other applications. In addition, this review also discusses the potential applications of oyster shells in industry, agriculture and medicine in the near future.
Key words: Biological    resources    of    oyster    shells    Water    body    restoration    Soil    improvement    Biomass    antibacterial    Industrial    ecological    raw    materials
收稿日期: 2022-09-16 出版日期: 2022-12-07
ZTFLH:  Q819  
基金资助: *山西省青年科技研究基金(201901D211084)
通讯作者: **电子信箱:523481558@qq.com; yangdp@qztc.edu.cn   
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张琪
张益霞
薛彩丽
张辉
张云鹏
杨大鹏

引用本文:

张琪, 张益霞, 薛彩丽, 张辉, 张云鹏, 杨大鹏. 海蛎壳生物质资源再利用的研究进展*[J]. 中国生物工程杂志, 2022, 42(11): 126-139.

ZHANG Qi, ZHANG Yi-xia, XUE Cai-li, ZHANG Hui, ZHANG Yun-peng, YANG Da-peng. Research Progress on Reuse of Biomass Resource of Oyster Shells. China Biotechnology, 2022, 42(11): 126-139.

链接本文:

https://manu60.magtech.com.cn/biotech/CN/10.13523/j.cb.2209044    或    https://manu60.magtech.com.cn/biotech/CN/Y2022/V42/I11/126

省 产量/万吨 占比/% 排名
福建 201.259 38.5 第一
广东 113.916 21.8 第二
山东 86.987 16.6 第三
广西 65.928 12.6 第四
辽宁 27.390 5.2 第五
浙江 22.771 4.3 —
江苏 4.020 7.7 —
河北 0.15 0.03 —
总产量 522.421 — —
表1  中国各省海蛎养殖产量[10]
图1  海蛎壳生物质资源应用领域
图2  海蛎壳的微观结构(a)[13]和“砖-泥”结构示意图(b)[14]
图3  渗透性海蛎壳砖的制备过程(编译自参考文献[25])
图4  壳聚糖对革兰氏阴性菌(a)和革兰氏阳性菌的作用模式(b)(编译自参考文献[54])
图5  天然海蛎壳SEM图像 [78]
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