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中国生物工程杂志

CHINA BIOTECHNOLOGY
中国生物工程杂志  2008, Vol. 28 Issue (3): 64-68    
论文     
废啤酒酵母吸附水溶液中Cu2+的性能及机理研究
王喜 甘树应 葛春丽 崔龙哲
中南民族大学化学与材料科学学院催化材料科学湖北重点实验室 上海环境科学研究院 中南民族大学化学与材料科学学院催化材料科学湖北重点实验室 中南民族大学化学与材料科学学院催化材料科学湖北重点实验室
Adsorption performance and mechanism of binding Cu(Ⅱ)on Saccharomyces cerevisiae
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摘要:

用废啤酒酵母吸附水溶液中Cu2+,考察了溶液pH值、Cu2+浓度和吸附时间对Cu2+吸附的影响。结果表明:废啤酒酵母吸附Cu2+在4-6个小时内达到吸附平衡,酸性条件利于吸附,以pH为5时最佳,吸附等温曲线符合Langmuir模式。用电位滴定及FTIR分析的方法确定生物吸附剂主要含有磺酸基、羧基及氨基等功能团。生物吸附剂对Cu2+的吸附以单分子层的化学吸附为主,功能团在不同的pH条件下呈现不同的电离性能,在吸附过程中发挥重要作用。

关键词: 生物吸附废啤酒酵母Cu2+官能团    
Abstract:

Saccharomyces cerevisiae was used as a new type of biosorbent for the removal of copper. Various experimental parameters (e.g. equilibrium pH, contact time, Cu2+ concentration) were investigated. The biosorption of Cu2+ by saccharomyces cerevisiae is a quick process which only need 4-6 hours to reach the equilibrium, and the optimum pH is 5.It is indicated that Langmuir isotherm sorption model is suitable for the isotherm adsorption of copper. Sulfonate, carboxyl and amine groups were present in the biosorbent, which was confirmed by FTIR and proton-binding model. Chemical sorption was dominated in the binding of its molecules. Different functional groups were ionized in different pH conditions and played a pronounced role in the sorption.

Key words: biosorption    saccharomyces cerevisiae    Cu2+    functional groups
收稿日期: 2007-11-19 出版日期: 2008-03-28
通讯作者: 崔龙哲   
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甘树应
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引用本文:

王喜,甘树应,葛春丽,崔龙哲. 废啤酒酵母吸附水溶液中Cu2+的性能及机理研究[J]. 中国生物工程杂志, 2008, 28(3): 64-68.

. Adsorption performance and mechanism of binding Cu(Ⅱ)on Saccharomyces cerevisiae. China Biotechnology, 2008, 28(3): 64-68.

链接本文:

https://manu60.magtech.com.cn/biotech/CN/        https://manu60.magtech.com.cn/biotech/CN/Y2008/V28/I3/64

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